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10px; } </style> <div id="ayccq4o" class="nyxqnewsbg"> <div id="4i0iwic" class="nyxqnews"> <div id="yiweoc0" class="nyxqnews_left"> <div id="yowiyoc" class="news_lefttit"> <h1>二噁英脫除催化劑的研究現狀及展望</h1> <span id="gwa0iwi" class="chuchu">點(diǎn)擊數：664</span> <span id="uoc4akw" class="shijian">發(fā)表時(shí)間：2022-05-14 15:48:26</span> <div id="qcocqeu" class="cl"></div> </div> <div id="ogseoeu" class="nyxqnews_leftcont"> <p> 隨著(zhù)各國城市化進(jìn)程的迅猛發(fā)展，產(chǎn)生的垃圾越來(lái)越多，垃圾焚燒處理由于其垃圾無(wú)害化、資源化、減量化程度高，被認為是目前垃圾處理的一種高效手段，已成為目前各國處理廢棄物主要和有效的技術(shù)之一。</p><p> 但垃圾在焚燒過(guò)程中不可避免地會(huì )產(chǎn)生大量污染物，如顆粒物、HCl、NOx、重金屬以及二噁英等。這些污染物對人體健康存在著(zhù)極大的危害，尤其是二噁英，具有劇毒，其毒性是氰化鉀的1000倍，1g二噁英就能置10000人于死地。</p><p> 此外，二噁英還具有致癌性、致畸性、致突變等慢性毒性。據統計，在全球范圍內，由垃圾焚燒爐排放出的二噁英約占二噁英總排放量的10%～40%。</p><p style="text-align: center;"><img src="/static/upload/image/20220514/1652514589174206.jpg" title="" alt=""/></p><p> 鑒于二噁英的極大毒性，國內外對其排放做出了嚴格的限定：美國、日本、德國等對二噁英的排放限值為0.1ngTEQ/m3;韓國為0.5ngTEQ/m3，而其首都首爾為0.1ngTEQ/m3。</p><p> 我國現有標準為1.0ngTEQ/m3，遠落后于發(fā)達國家，最新《生活垃圾焚燒污染標準》(二次征求意見(jiàn)稿)將排放限值降到0.1ngTEQ/m3，預計從2014年7月1日起實(shí)施。</p><p> 目前，我國垃圾焚燒技術(shù)發(fā)展很迅速，生活垃圾焚燒技術(shù)已被越來(lái)越多的大中城市選用。另外，醫院垃圾必須采用焚燒方法進(jìn)行處理，特別是非典過(guò)后，對醫院垃圾的處理提出了更高的要求。因此，對于新的二噁英去除技術(shù)需求越來(lái)越迫切。</p><p> 目前，垃圾焚燒主要采用活性炭吸附去除煙氣里的二噁英，但是用活性炭吸附法減少多氯二苯并二噁英(PCDDs)和多氯二苯并呋喃(PCDFs)的排放，運行成本高，且未能從根本上解決問(wèn)題，PCDDs和PCDFs還是存在的，必須進(jìn)行專(zhuān)門(mén)的處理，而有的企業(yè)為降低成本，只是進(jìn)行了填埋，對地下水更是存在極大安全隱患，而且凈化效率不如催化凈化法高，難以達到更高的排放要求。</p><p> 而催化凈化技術(shù)具有反應溫度低、節省能源、可以處理低含量的有機污染物、去除效率高而且分解效果穩定等特點(diǎn)，因此催化去除二噁英類(lèi)污染物成為研究的主要方向。</p><p> 1二噁英催化劑凈化去除機制</p><p style="text-align: center;"><img src="/static/upload/image/20220514/1652514597175641.jpg" title="" alt=""/></p><p> 二噁英是由兩個(gè)苯環(huán)通過(guò)氧原子連接而生成的芳香烴族化合物，是PCDDs和PCDFs兩類(lèi)化合物的總稱(chēng)。二噁英催化凈化指在有氧的環(huán)境下，二噁英吸附在催化劑的表面上，在催化劑活性位置發(fā)生催化氧化反應，使二噁英被分解生成CO2、H2O、HCl、H2O等無(wú)機產(chǎn)物的過(guò)程。二噁英催化氧化的反應原理方程式：</p><p> 常用催化劑有貴金屬催化劑和過(guò)渡金屬氧化物催化劑。貴金屬催化劑活性高，但價(jià)格昂貴，且由于垃圾焚燒尾氣煙氣含有大量的HCl和SO2，貴金屬催化劑很容易發(fā)生中毒，甚至在反應過(guò)程中可能產(chǎn)生毒性更高的產(chǎn)物。而氧化釩催化劑既可以催化消除NOx，同時(shí)也可以高效氧化去除有機污染物，更加經(jīng)濟有效。</p><p> 2國內外釩-鈦二噁英催化劑分解技術(shù)研究進(jìn)展</p><p> 自從HAGENMAIER首先報道用于選擇性催化還原法(SCR)脫硝催化劑V2O5-WO3-TiO2和V2O5-MoO3-TiO2對PCDDs和PCDFs具有顯著(zhù)的催化降解活性，開(kāi)啟了SCR催化劑對二噁英去除的研究。</p><p> KRISHNAMOORTHY等對比了不同釩含量V2O5-TiO2催化劑對鄰二氯苯的影響，發(fā)現高釩量比低釩量催化劑活性高，尾氣只檢測出CO2和CO，CO的選擇性為40%～45%，而且WO3、MoO3及ZnO的加入對V2O5-TiO2的1，2-二氯苯催化氧化性能沒(méi)有影響。</p><p style="font-family: 微軟雅黑;line-height: 1.5em;"><br/></p> </div> <div id="qa0eugy" class="nyxqnews_leftpage"> 上一篇：沒(méi)有了！下一篇：<a href="/cjwt/1423.html">SPS高比表氫氧化鈣與小蘇打使用對比</a> </div> </div> <div id="ocqau0e" class="nyxqnews_right"> <div id="00cweog" class="nyxqnewsfanhui"> <a href="#"><img src="/template/moban/images/newsback.png" alt=""></a> </div> <div id="iuguimy" class="nywenzhang"> <div id="gs0uiug" class="nyxqnews_righttit">精選<strong>文章</strong></div> <div id="kaws0ka" 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