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2em;">CO2降低了沼氣的能量密度，通過(guò)去除CO2可以提高單位體積氣體的能量值，此外，去除CO2也可以提高沼氣品質(zhì)。如果所用的沼氣需要達到天然氣標準或者被用作汽車(chē)燃料，那么就必須對其中的CO2進(jìn)行去除；如果只作為一般的沒(méi)有特殊要求的用途，則沒(méi)有必要脫除CO2。</p><p style="text-indent: 2em;">1.<span style="text-indent: 2em;">物理吸收法</span></p><p style="text-indent: 2em;">采用物理溶劑吸收CO2，沒(méi)有形成新的化合物。其中一種方法采用甲醇作為吸收劑，其工藝特點(diǎn)是不會(huì )加濕原料并且再生能耗低。在再生階段，CO2從物理溶劑中閃蒸出來(lái)，貧溶劑用泵打回吸收塔。</p><p style="text-indent: 2em;">物理溶劑吸收法特別適合重烴含量少的貧氣，這是因為甲烷在甲醇中的溶解度只是CO2在甲醇中溶解度的40%，而丙烷在甲醇中的溶解度與CO2的相近，因此需要一個(gè)循環(huán)系統以提高氣體的回收率。</p><p style="text-indent: 2em;">物理溶劑吸收法還可采用無(wú)水碳酸丙烯脂等溶劑，但從目前的大中型沼氣工程的投資和效益來(lái)考慮，還是不適用的。</p><p style="text-indent: 2em;">(1)水洗法</p><p style="text-indent: 2em;">水洗法是利用CO2和H2S在水中溶解度與甲烷的差異，通過(guò)物理吸收過(guò)程，實(shí)現CO2和H2S與甲烷的分離。通常沼氣經(jīng)壓縮后從吸收柱底部進(jìn)入，水從頂部進(jìn)人進(jìn)行反相流動(dòng)吸收。為提高CO2在水中的溶解度，水洗工藝一般采用較高壓力，吸收了CO2和H2S的水可以再生循環(huán)使用，可以在吸收柱中通過(guò)減壓或者用空氣吹脫再生，增加了運行成本。</p><p style="text-indent: 2em;">吸收過(guò)程需要大量純化工業(yè)用水，產(chǎn)生的廢水需進(jìn)行回收處理，凈化后氣體也需干燥處理，設備比較復雜。此外，當水中的H2S濃度比較高的時(shí)候，一般不推薦使用空氣吹脫，因為水很快又會(huì )被硫污染。如果有廢水可以利用，不推薦對水進(jìn)行再生。</p><p style="text-indent: 2em;">(2)聚乙二醇洗滌法</p><p style="text-indent: 0em; text-align: center;"><img src="/static/upload/image/20220514/1652513078156417.jpg" title="沼氣脫碳脫水之物理吸收法！" alt="沼氣脫碳脫水之物理吸收法！"/></p><p style="text-indent: 2em;">聚乙二醇洗滌和水洗一樣也是一個(gè)物理吸收過(guò)程?，F多采用一種商品名為Selexol的溶劑，主要成分為二甲基聚乙烯乙二醇。和在水中一樣，CO2和H2S在Selexol溶劑中的溶解度比甲烷大，不同之處是CO2和H2S在Selexol溶劑中的溶解度比水中大，這樣所需Selexol的量也會(huì )減少，更加經(jīng)濟和節能。另外，水和鹵代烴(填埋場(chǎng)沼氣中的成分)也可以用Selexol洗滌去除。</p><p style="text-indent: 2em;">可以使用水蒸氣或者惰性氣體(凈化后的沼氣和天然氣) 吹脫Selexol中的元素硫，但是不推薦使用空氣。</p><p style="text-indent: 2em;">(3) 膜分離法</p><p style="text-indent: 2em;">氣體膜分離技術(shù)的基本原理是根據混合氣體中各組分在壓力的推動(dòng)下透過(guò)膜的傳遞速率不同，從而達到分離的目的。</p><p style="text-indent: 2em;">膜法分離主要有兩種方法：一種是膜的兩邊都是氣相的高壓氣體分離；另一種是通過(guò)液體吸收擴散穿過(guò)膜的分子的低壓氣相-液相吸收分離。</p><p style="text-indent: 2em;">①高壓氣相分離法</p><p style="text-indent: 2em;">將壓縮到3.6X106帕的沼氣首先通過(guò)活性炭床以去除鹵代烴和H2S，接著(zhù)通入濾床和加熱器。膜是由醋酸纖維素制成，可以用來(lái)分離像CO2，水蒸氣和殘留的H2S等極性分子，它有一定的選擇性，即在不同的區域吸收H2S和CO2，但不能分離甲烷中的N2。</p><p style="text-indent: 2em;">經(jīng)驗表明，膜可以持續使用三年，在使用一年半后，因為萎縮的緣故，膜的滲透性會(huì )減少30%。</p><p style="text-indent: 2em;">②氣相-液相吸收膜分離法</p><p style="text-indent: 0em; text-align: center;"><img src="/static/upload/image/20220514/1652513085508593.jpg" title="沼氣脫碳脫水之物理吸收法！" alt="沼氣脫碳脫水之物理吸收法！"/></p><p style="text-indent: 2em;">氣相-液相吸收膜工藝實(shí)質(zhì)是沼氣中的H2S和CO2分子穿過(guò)一個(gè)多孔的疏水膜在液相中被吸收去除，從吸收膜下方進(jìn)入的氣體，其中的H2S和CO2分子能夠擴散穿過(guò)膜，然后被相反方向流過(guò)的液體吸收，吸收膜在一個(gè)標準大氣壓下工作。</p><p style="text-indent: 2em;">在25~35℃，可以非常有效地把沼氣中的H2S濃度從2%減少到小于250ml/m3，液相的吸收劑可以用NaOH溶液。</p><p style="text-indent: 2em;">由于氣體分離效率多受膜材料、氣體組成、壓差、分離系數以及溫度等多種因素的影響，且對原料氣的清潔度有一定要求，膜組件價(jià)格昂貴，膜分離法中使用的膜需要經(jīng)常更換，運行成本較高。因此，氣體膜分離法一般不單獨使用，常和溶劑吸收、變壓吸附、深冷分離、滲透蒸發(fā)等工藝聯(lián)合使用。</p><p style="font-family: 微軟雅黑;line-height: 1.5em;"><br/></p> </div> <div id="5pzzzbd" 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