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15:28:41</span> <div id="xxhxxdr" class="cl"></div> </div> <div id="fjdrtjp" class="nyxqnews_leftcont"> <p style="text-indent: 2em;">天然氣中含有H2S,是有害物質(zhì)，它的存在一方面引起設備與管道腐蝕、催化劑中毒，另一方面嚴重的影響人身安全,是必須消除的污染物。目前，天然氣脫硫技術(shù)開(kāi)發(fā)了許多方法,硫化氫是無(wú)色氣體、有刺激性惡臭、易揮發(fā)，燃燒時(shí)呈藍色火焰。硫化氫是大氣的主要污染物之一，不僅危害人體健康，還會(huì )嚴重腐蝕設備等。硫化氫治理開(kāi)始較早，1809年英國克萊格使用石灰乳凈化器脫硫，1849年英國蘭寧和希爾斯獲得干式氧化鐵法專(zhuān)利，1870 年美國發(fā)展了氧化鐵制備方法，年代山式鋼化鐵法在脫硫領(lǐng)域沿用100年之久。20 世紀30 年代一40年代出現溶液法，將氫氧化鐵懸浮在堿液中進(jìn)行脫硫;50 年代起，西歐普遍采用氨水法;60 年代出現砷堿法，用砷化物作催化劑。因砷化物有劇毒，逐漸為無(wú)毒催化劑所取代。如對苯二酚法、A.D.A.法、富瑪克斯法、達克哈克斯法等都使用無(wú)毒催化劑,這些方法都是近年發(fā)展較快的技術(shù)。此外，溶液法的吸收廢液處理技術(shù)也不斷發(fā)展，形成了不同的脫硫工藝，主要有如下四類(lèi):</p><p style="text-indent: 0em; text-align: center;"><img src="/static/upload/image/20220514/1652513494106549.jpg" title="天然氣脫硫技術(shù)有哪些？（上）" alt="天然氣脫硫技術(shù)有哪些？（上）"/></p><p style="text-indent: 2em;">1.可再生溶劑吸收法</p><p style="text-indent: 2em;">通過(guò)可再生溶劑吸收天然氣中的H2S 是最常用的方法，含H2S 的天然氣與溶劑通過(guò)逆流接觸在吸收塔中將其脫除，同時(shí)吸收H2S 的副液通過(guò)再生將其除去,重新使用。再生出的酸氣通過(guò)硫磺回收工藝將H2S轉化成硫磺產(chǎn)品。常用的溶劑有化學(xué)溶劑、物理溶劑和混合溶劑。</p><p style="text-indent: 2em;">1) 化學(xué)溶劑法</p><p style="text-indent: 2em;">醇胺類(lèi)化學(xué)溶劑是天然氣脫硫最常見(jiàn)的方法,在低壓控制中適用,而且溶劑對烴的溶解度很小，不會(huì )造成烴的損失。醇胺法氣體脫硫技術(shù)從溶劑生產(chǎn)、配制、配方、供應以及工藝技術(shù)咨詢(xún)服務(wù)已專(zhuān)業(yè)化、商品化，如美國的聯(lián)合碳化物公司、德國的巴斯夫公司等。主要是MODEA法，還有MEA、DEA、DIPA 等方法。脫硫效果是凈化氣中H2S 的含量由0.005%降到0.002%。</p><p style="text-indent: 0em; text-align: center;"><img src="/static/upload/image/20220514/1652513502178489.jpg" title="天然氣脫硫技術(shù)有哪些？（上）" alt="天然氣脫硫技術(shù)有哪些？（上）"/></p><p style="text-indent: 2em;"> 熱碳酸鉀法成功地應用到從氣體脫除大量CO2 到用來(lái)脫除CO2</p><p style="text-indent: 2em;">和H2S。</p><p style="text-indent: 2em;">2) 物理溶劑法</p><p style="text-indent: 2em;">使用物理溶劑進(jìn)行天然氣脫硫的過(guò)程沒(méi)有化學(xué)反應發(fā)生,溶劑的循環(huán)過(guò)程主要是進(jìn)料氣量、吸收壓力以及溫度的函數。此外，大多數物理溶劑對H2S 均展示一定的選擇脫除能力。缺點(diǎn)是:它對重烴的溶解度很大，重烴含量高的天然氣不易使用。物理溶劑吸收法主要包括N 甲基吡咯烷酮法(Purisol 法)、聚乙二醇二甲醚法(Selexol 法)、磷酸三丁酯法(Estasovan 法)、N 甲基一已內酰胺法(NMC法)等。Purisol 法使用的溶劑是N 甲基吡咯烷酮( NMP),它沸點(diǎn)很高，對于H,S的溶解度很大，特別適用于有CO2存在的脫硫。Seled法使用的溶劑是聚乙二醇二甲醚，它同時(shí)脫去天然氣中的CO2和H2S,對H2S的溶解度遠遠大于CO2,同時(shí)還有一定的脫水性。Estasolvan 法使用的溶劑是磷酸三丁酯(TBP)，是德國Friedrich Unde 公司提出的用于脫硫和回收烴。TBP對H2S 比對CO2 更具選擇性,可將天然氣處理到管輸標準。</p><p style="font-family: 微軟雅黑;line-height: 1.5em;"><br/></p> </div> <div id="pt51xnr" class="nyxqnews_leftpage"> 上一篇：沒(méi)有了！下一篇：<a href="/xyzx/1418.html">天然氣脫硫技術(shù)有哪些？（下）</a> </div> </div> <div id="zvj55vj" class="nyxqnews_right"> <div id="td5xh55" class="nyxqnewsfanhui"> <a href="#"><img src="/template/moban/images/newsback.png" alt=""></a> </div> <div id="vnbrdrn" class="nywenzhang"> <div id="zlnlfzp" class="nyxqnews_righttit">精選<strong>文章</strong></div> <div id="jt5vthv" class="nyxqnews_rightcont"> <a href="/xyzx/1506.html" title="煙氣脫硫劑的用途及性能特點(diǎn)">煙氣脫硫劑的用途及性能特點(diǎn)</a> <a href="/xyzx/1505.html" title="煙氣脫硫劑有效脫除二氧化硫廢氣">煙氣脫硫劑有效脫除二氧化硫廢氣</a> <a href="/xyzx/1504.html" title="SCR脫硝催化劑到底是什么呢？">SCR脫硝催化劑到底是什么呢？</a> <a 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