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""; width: 75px; height: 1px; background: #1059a9; position: absolute; left: 0; bottom: -1px; } .nyxqnews_righttit strong { color: #1059a9; } .nyxqnews_rightcont { margin-top: 10px; line-height: 36px; } .nyxqnews_rightcont a { display: block; background: url(/template/moban/images/newswenzhagn.png) left center no-repeat; padding-left: 22px; width: 220px; height: 36px; overflow: hidden; } .nyzx { margin-top: 10px; } </style> <div id="uig0u0q" class="nyxqnewsbg"> <div id="myeum4w" class="nyxqnews"> <div id="coascuy" class="nyxqnews_left"> <div id="4mg4kyi" class="news_lefttit"> <h1>天然氣脫硫技術(shù)有哪些？（下）</h1> <span id="oqm4qcm" class="chuchu">點(diǎn)擊數：516</span> <span id="c0c004s" class="shijian">發(fā)表時(shí)間：2022-05-14 15:32:04</span> <div id="4ewig4y" class="cl"></div> </div> <div id="kukwawq" class="nyxqnews_leftcont"> <p style="text-indent: 2em;">3) 混合溶劑法</p><p style="text-indent: 2em;"> 混合溶劑法是將物理溶劑與化學(xué)溶劑相混合，將化學(xué)溶劑獲得軟高處理氣純度和物理溶劑再生過(guò)程需熱量較小相結合。同時(shí)，由于華理溶劑的參與使混合液在較高的酸氣分壓下有較高的酸氣負荷力外，由于蒸汽壓和溶劑降解引起的溶劑損失也很小但其價(jià)格較高。</p><p style="text-indent: 2em;">2.固定床脫硫法</p><p style="text-indent: 2em;">固定床脫硫法主要用于除去天然氣低H2S 含量或痕量時(shí)的脫硫。整個(gè)過(guò)程是基于某些多孔介質(zhì)的吸附特性而進(jìn)行的，有時(shí)還將這些多孔介質(zhì)用一些反應性的化學(xué)物質(zhì)進(jìn)行浸漬處理。這些過(guò)程一般都是應用于選擇性H2S 脫除的?？稍偕摿騽┯谢钚蕴?、活性氧化鋁、硅股、合成沸石;不可再生脫硫劑有氧化鋅。</p><p style="text-indent: 0em; text-align: center;"><img src="/static/upload/image/20220514/1652513608170433.jpg" title="" alt=""/></p><p style="text-indent: 2em;">1) 活性炭法</p><p style="text-indent: 2em;">活性炭是最常用的固體脫硫劑,用來(lái)除去天然氣中的微量H2S,優(yōu)點(diǎn)是: 比表面和微孔發(fā)達、熱穩定性好、在濕氣中吸附率高、價(jià)格低、能吸收有機硫化物。吸收有機硫化物(硫醇、硫醚、CS2 、COS) 的活性炭其微孔數量比大孔多很多，平均孔徑小于6nm。吸收無(wú)機硫化物的活性炭其微孔數量與大孔大致相同,平均孔徑8mm- 20nm。脫硫后的活性炭用150℃-180℃的蒸汽再生，活性炭在150℃以上開(kāi)始再生放出硫化物。用活性炭吸附硫化氫，通氧氣轉換成單體硫和水，用硫化胺洗去硫磺，活性炭可繼續使用。此法不宜用于含焦油的氣體。 </p><p style="text-indent: 2em;">2) 分子篩法</p><p style="text-indent: 2em;">早在1958 年美國聯(lián)合碳化物公司開(kāi)始研究此技術(shù)，目前,已廣泛用于脫除氣體中的H2S 和其他硫化物。如合成沸石分子篩可用于天然氣選擇性脫除H2S 和其他硫化物。天然氣中的硫化物比其他組分有更高的沸點(diǎn)和更大的極性,分子篩對極性分子的吸附選擇性對硫化物產(chǎn)生高的容量。由于它對有機硫化物同對H2S一樣具有很大的化學(xué)親和力，所以,分子篩不僅除去H2S,而且對CS2、硫醇等也有很好的脫除效率,處理后的氣體中硫質(zhì)量分數下降至4×10-7。</p><p style="text-indent: 2em;">3) 氧化鋅法</p><p style="text-indent: 0em; text-align: center;"><img src="/static/upload/image/20220514/1652513615118664.jpg" title="" alt=""/></p><p style="text-indent: 2em;">氧化鋅是用于脫除天然氣中微量H2S 的有效脫硫劑，一般是做成球狀體填充于固定床中，與硫化氫反應生成硫化鋅和水,其反應不可逆,反應完全后重新裝填硫化鋅顆粒。此方法可將H2S 脫除到質(zhì)量分數2×10-7。</p><p style="text-indent: 2em;">4) 氫氧化鐵法</p><p style="text-indent: 2em;">將鐵屑和濕木屑充分混合，加0.5% 氧化鈣，制成脫硫劑，相對濕度為30%-40%。硫化氫同脫硫劑反應而被脫除，再生的氫氧化鐵可繼續使用。其反應如下:</p><p style="text-indent: 2em;">2Fe( OH) + 3H2S ->FeS +6H2O</p><p style="text-indent: 2em;">2FeS +6H2O +302 -4Fe(OH) +6S<span style="text-indent: 2em;">此法脫硫效率高，適于凈化硫化氫含量低的氣體;但設備占地面積大，脫硫劑必須定期再生和更換，操作條件差。因而已逐漸為濕法取代，或同濕法聯(lián)合用于深度脫硫。</span></p><p style="font-family: 微軟雅黑;line-height: 1.5em;"><br/></p> </div> <div id="w0igqks" class="nyxqnews_leftpage"> 上一篇：<a href="/xyzx/1417.html">天然氣脫硫技術(shù)有哪些？（上）</a> 下一篇：<a href="/xyzx/1419.html">這樣做到底有多危險？</a> </div> </div> <div id="ae0gqkc" class="nyxqnews_right"> <div id="kykeoe0" class="nyxqnewsfanhui"> <a href="#"><img src="/template/moban/images/newsback.png" alt=""></a> </div> <div id="g0o0ic0" class="nywenzhang"> <div id="460qkio" class="nyxqnews_righttit">精選<strong>文章</strong></div> <div id="gc0issm" class="nyxqnews_rightcont"> <a href="/xyzx/1506.html" title="煙氣脫硫劑的用途及性能特點(diǎn)">煙氣脫硫劑的用途及性能特點(diǎn)</a> <a href="/xyzx/1505.html" title="煙氣脫硫劑有效脫除二氧化硫廢氣">煙氣脫硫劑有效脫除二氧化硫廢氣</a> <a href="/xyzx/1504.html" title="SCR脫硝催化劑到底是什么呢？">SCR脫硝催化劑到底是什么呢？</a> <a href="/xyzx/1503.html" title="脫硝催化劑的組成有哪些？">脫硝催化劑的組成有哪些？</a> </div> </div> </div> </div> <div id="qw4ocyw" class="cl"></div> </div> </div> </div> <div class="qscymw4" id="right">  </div> <div id="4gasmis" class="clear"></div> </div>  <div class="oossou0" id="copy"> <script 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